I made a booking and i am on the page where it says add order. Now the customer wants the tax invoice to be sent to her e mail id and she gave it to me just before clicking ADD NEW order. What do I do.

You should have confirmed the email address before this.  But in the final payment window up the top right you will see email addresses.

click on the + button and then add her email address there

when you finish the booking.  go to the customer detail page and add the email address of the customer in the work email field of the customer account.